This application note shows the various relationships and methods needed to extract the diffusion coefficient of an inserted species into a host electrodes using Electrochemical Impedance Spectroscopy (EIS), Potentiostatic Intermittent Titermittent Technique (PITT) and Galvanostatic Intermittent Titration technique (GITT). The main results are that when the system is composed of several charge transfer resistances and double layer capacitances, only EIS can simply lead to the diffusion time constants and hence diffusion coefficients.
Looking for something?
Results in
Document.
Determination of the diffusion coefficient of an inserted species in a host electrode with EIS, PITT and GITT techniques Battery – Application Note 70
Precision and Accuracy in Coulombic Efficiency Measurements (High Precision Coulometry HPC) Battery – Application Note 53
AN54. High Precision Coulometry HPC. Battery Cycling/Electrochemistry
BT-Lab Technical Notes 46: How to properly use the dummy cells for BCS-800
This document will present you how to properly use the Dummy Cells to verify BCS modules.
DC and AC characterization of a Vanadium Redox Flow Battery (VRFB) using a Pinflow 20 cm² test lab cell Battery – Application Note 71
The characterization of Vanadium Redox Battery Cells using BioLogic BCS-815 battery cyclers & a Pinflow® 20 cm² test cell.
Premium Potentiostat Range
Brochure detailing the full Premium range of BioLogic potentiostat / galvanostats
EC-Lab® & BCS-800 with BT-Lab® graphic customization Battery – Application Note 26
AN26, EC-Lab & BT-Lab graphic customization, Electrochemistry
How to measure the ohmic resistance of a battery using EIS (EIS-high-frequency-internal-resistance) Battery – Application Note 62
AN62. EIS high frequencies internal resistance. Electrochemistry
BT-Lab Technical Note 49: Measurements with BCS-800 & BT-Lab® software starting from a negative Ecell value
When working with BCS systems, two validations are necessary when trying to begin a technique with a battery whose initial potential is negative.
EC-Lab Technical Notes 47: How to use sequences, loops, and cycles in EC-Lab® and BCS-800’s BT-Lab® software?
The differences between cycles, loops and sequences and how they can be used to configure cleaner, more structured experiments and simplified data display/analysis
Galvanostatic Cycling with Potential limitation 4: Low Earth Orbit (LEO) battery satellite protocol (GITT#2) Battery – Application Note 3
AN3. GCPL 4 protocol in the field of battery testing. Electrochemistry
The modified inductance element $L_\text a$ Battery – Application Note 42
AN42. Battery-EIS modified inductance element. Electrochemistry
Battery cycling with reference electrodes using the PAT-cell test cell Battery – Application Note 58
AN58. Reference electrode. Electrochemistry
Potentio or Galvano EIS Battery – Application Note 49
AN49. Potentio or Galvano EIS Electrochemistry
How to interpret lower frequencies impedance in batteries (EIS low frequency diffusion) Battery – Application Note 61
AN61. EIS low frequencies diffusion - Battery. Electrochemistry
Dynamic resistance determination. A relation between AC and DC measurements? EIS & Battery – Application Note 38
AN38. Internal resistance determination EIS. Electrochemistry
Differential (Incremental) Capacity Analysis Battery – Application Note 40
AN40. DCS & DCA - Battery. Electrochemistry
A comprehensive solution to address battery module/pack Energy Storage – Application Note 59
AN59. Pack fuel cell/ stack module battery. Electrochemistry
Interpretation problems of impedance measurements on time variant systems Battery & Corrosion – Application Note 55
AN55. EIS stationarity - Electrochemistry, Battery & Corrosion. Electrochemistry
Differential Coulometry Spectroscopy (DCS) Battery – Application Note 57
AN57. DCS & DCA. Electrochemistry
Constant power technique and Ragone plot Battery & Electrochemistry – Application Note 6
AN6. Ragone plot. Electrochemistry
Ohmic Drop Part II: Intro. to Ohmic Drop measurement techniques (Ohmic drop measurement) Battery – Application Note 28
AN28, Ohmic drop measurement techniques, Electrochemistry
Protocols for studying intercalation electrodes materials- I: Galvanostatic cycling/potential limitations (GCPL) GITT Battery – Application Note 1
AN 1. GITT - Electrochemistry & Battery Application. Electrochemistry
Drift correction in electrochemical impedance measurements (EIS non stationarity) Battery – Application Note 17
AN17. EIS non stationarity - Electrochemistry, Battery & Corrosion. Electrochemistry
Using the SECM150 to Measure an NMC Battery Electrode Scanning Probes – Application Note 21
AN21. Measure an NMC Battery Electrode. Scanning probe electrochemistry
In situ measurements for shrinking/dilation in energy storage devices during cycling Battery – Application Note 46
AN46. Dilatometer - Electrochemistry & Battery. Electrochemistry
Impedance, admittance, Nyquist, Bode, Black, (EIS plot) Battery – Application Note 8
AN8. EIS plot – Electrochemistry & Battery. Electrochemistry
Protocols for intercalation electrodes materials-2, Potentiodynamic Cycling/Galvanostatic Acceleration (PCGA) PITT Battery – Application Note 2
AN 2. PITT - Electrochemistry & Battery. Electrochemistry
EIS measurements with multi sine Battery & Corrosion – Application Note 19
AN 19. EIS multi sine - Electrochemistry, Battery & Corrosion. Electrochemistry
EIS Quality Indicators: THD, NSD & NSR Battery & Corrosion – Application Note 64
AN64. EIS Quality Indicators: THD, NSD & NSR. Electrochemistry
Photosynthesis Technical Notes 01: Use of Eukaryote Kit in Absorbance mode – ECS measurement with PSI excitation
Use of Eukaryote Kit in Absorbance mode – ECS measurement with PSI excitation
EIS pseudocapacitance Battery & Corrosion – Application Note 20
AN 20. EIS pseudocapacitance - Electrochemistry, Battery & Corrosion. Electrochemistry
EC-Lab Technical Notes 38: BCD technique: Battery Capacity Determination
EC-Lab Technical Notes 38 Battery Capacity Determination
Fully Integrated Design of a Stretchable Solid‐State Lithium‐Ion Full Battery
Xi Chen Haijian Huang Long Pan Tian Liu Markus Niederberger
Synthetic vs. Real Driving Cycles: A Comparison of Electric Vehicle Battery Degradation
CITATION: George Baure and Matthieu Dubarry